§63.1365. Test methods and initial compliance procedures.
40 C.F.R. § 63.1365
(1) Periods when the streams contain the highest combined VOC and HAP hourly load, as described by the emission profiles in paragraph (b)(11)(iii) of this section; or
(2) Periods when the streams contain HAP constituents that approach the limits of solubility for scrubbing media; or
(3) Periods when the streams contain HAP constituents that approach the limits of adsorptivity for carbon adsorption systems.
(1) If all process vents for a process are controlled using a control device or series of control devices that reduce HAP emissions by 98 percent or more, no other emission streams are vented to the control device when it is used to control emissions from the subject process, and the performance test is conducted over the entire batch cycle.
(2) If a control device is used to comply with the outlet concentration limit for process vent emission streams from a single process (but not necessarily all of the process vents from that process), no other emission streams are vented to the control device while it is used to control emissions from the subject process, and the performance test is conducted over the entire batch cycle.
(1) If the components are miscible in one another, use Raoult's law to calculate the partial pressures;
(2) If the solution is a dilute aqueous mixture, use Henry's law constants to calculate partial pressures;
(3) If Raoult's law or Henry's law are not appropriate or available, use any of the methods specified in paragraphs (c)(2)(i)(A) (3)(i) through (iii) of this section.
(i) Use experimentally obtained activity coefficients;
(ii) Use models such as the group-contribution models to predict activity coefficients;
(iii) Assume the components of the system behave independently and use the summation of all vapor pressures from the HAP as the total HAP partial pressure;
(1) If the final temperature to which the vessel contents are heated is lower than 50 K below the boiling point of the HAP in the vessel, then emissions shall be calculated using Equations 11 through 14 of this subpart.
(i) The mass of HAP emitted per episode shall be calculated using Equation 11 of this subpart:
(ii) The moles of noncondensable gas displaced shall be calculated using Equation 12 of this subpart:
(iii) The initial and final pressure of the noncondensable gas in the vessel shall be calculated according to Equation 13 of this subpart:
(iv) The average molecular weight of HAP in the displaced gas shall be calculated using Equation 14 of this subpart:
(2) If the vessel contents are heated to a temperature greater than 50 K below the boiling point, then emissions from the heating of a vessel shall be calculated as the sum of the emissions calculated in accordance with paragraphs (c)(2)(i)(D)(2)(i) and (ii) of this section.
(i) For the interval from the initial temperature to the temperature 50 K below the boiling point, emissions shall be calculated using Equation 11 of this subpart, where T2 is the temperature 50 K below the boiling point.
(ii) For the interval from the temperature 50 K below the boiling point to the final temperature, emissions shall be calculated as the summation of emissions for each 5 K increment, where the emission for each increment shall be calculated using Equation 11 of this subpart. If the final temperature of the heatup is lower than 5 K below the boiling point, the final temperature for the last increment shall be the final temperature of the heatup, even if the last increment is less than 5 K. If the final temperature of the heatup is higher than 5 K below the boiling point, the final temperature for the last increment shall be the temperature 5 K below the boiling point, even if the last increment is less than 5 K.
(3) While boiling, the vessel must be operated with a properly operated process condenser. An initial demonstration that a process condenser is properly operated is required for vessels that operate process condensers without secondary condensers that are air pollution control devices. The owner or operator must either measure the condenser exhaust gas temperature and show it is less than the boiling point of the substance(s) in the vessel, or perform a material balance around the vessel and condenser to show that at least 99 percent of the material vaporized while boiling is condensed. Uncontrolled emissions are assumed to be zero under these conditions. The initial demonstration shall be conducted for all appropriate operating scenarios and documented in the Notification of Compliance Status report as specified in § 63.1368(f).
(4)(i) As an alternative to the procedures described in paragraphs (c)(2)(i)(D)(1) and (2) of this section, emissions caused by heating a vessel to any temperature less than the boiling point may be calculated using Equation 15 of this subpart.
(ii) The average gas space molar volume during the heating process is calculated using Equation 16 of this subpart.
(iii) The difference in the number of moles of total HAP in the vessel headspace between the initial and final temperatures is calculated using Equation 17 of this subpart.
(1) The moles of HAP vapor initially in the vessel are calculated using Equation 18 of this subpart:
(2) The initial and final moles of noncondensable gas present in the vessel are calculated using Equations 19 and 20 of this subpart:
(3) The initial and final partial pressures of the noncondensable gas in the vessel are determined using Equations 21 and 22 of this subpart.
(4) The moles of HAP emitted during the depressurization are calculated by taking an approximation of the average ratio of moles of HAP to moles of noncondensable and multiplying by the total moles of noncondensables released during the depressurization, using Equation 23 of this subpart:
(5) Use Equation 24 of this subpart to calculate the mass of HAP emitted:
(6) As an alternative to the procedures in paragraphs (c)(2)(i)(E)(1) through (5) of this section, emissions from depressurization may be calculated using Equation 25 of this subpart:
(1) Use of material balances based on process stoichiometry to estimate maximum organic HAP concentrations;
(2) Estimation of maximum flow rate based on physical equipment design such as pump or blower capacities; and
(3) Estimation of HAP concentrations based on saturation conditions.
(2) The initial and final volumes of noncondensable gas present in the vessel, adjusted to the pressure of the receiver, are calculated using Equations 31 and 32 of this subpart.
(3) Initial and final partial pressures of the noncondensable gas in the vessel are determined using Equations 33 and 34 of this subpart.
Debits and all terms of Equation 40 of this subpart are in units of Mg/month
(1) The term “90 percent reduction” shall apply instead of the term “98 percent reduction”; and
(2) When the phrase “paragraph (g)(2)” is referred to in § 63.150(h)(2)(iii) and (iv), the provisions in paragraph (h)(5)(ii) of this section shall apply for the purposes of this subpart.
Notes, amendments, and revision history
Amendments
[64 FR 33589, June 23, 1999, as amended at 67 FR 59347, Sept. 20, 2002; 79 FR 17374, Mar. 27, 2014]
Source
Source: 64 FR 33589, June 23, 1999, unless otherwise noted.
Authority
Authority: 42 U.S.C. 7401 et seq.
Source
Source: 57 FR 61992, Dec. 29, 1992, unless otherwise noted.
Amendments
[64 FR 33589, June 23, 1999, as amended at 67 FR 59347, Sept. 20, 2002; 79 FR 17374, Mar. 27, 2014]